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Hard–soft synthesis of a new series of vacancy-ordered perovskites, CaCrO 3− δ

    Home Publications Hard–soft synthesis of a new series of vacancy-ordered perovskites, CaCrO 3− δ
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    Hard–soft synthesis of a new series of vacancy-ordered perovskites, CaCrO 3− δ

    By Mark | Publications | Comments are Closed | 15 February, 2016 | 0

    Angel M. Arevalo-Lopez, Bing Liang, Mark S. Senn, Claire Murray, Chiu Tang and J. Paul Attfield, J. Mater. Chem. C, 2 (2014), 9364-9367.

    New CaCrO3d superstructure phases (d ¼ 0.33, 0.4, and 0.5) have been discovered through ‘soft’ low temperature reduction of the perovskite CaCrO3 made at ‘hard’ high pressure–temperature conditions. Their structures form a related series based on stacking of octahedral and tetrahedral chromium oxide layers.

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    Mark

    Principal Investigator

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