
A novel symmetry-adapted pair distribution function analysis (SAPA) method for extracting information on local distortions from pair distribution function data is introduced.

Improper ferroelectric materials are increasingly under investigation for their potential to expand the catalogue of functional ferroelectrics and couple with properties such as ferromagnetism.

Hybrid improper ferroelectrics (HIFs) have been studied intensively over the past few years to gain an understanding of their temperature-induced phase transitions and ferroelectric switching pathways.

We use a symmetry-motivated approach to analysing X-ray pair distribution functions to study the mechanism of negative thermal expansion in two ReO3-like compounds; ScF3 and CaZrF6.

By tuning the tolerance factor, t, of the Ruddlesden–Popper oxide Ca2MnO4 through isovalent substitutions, we show that the uniaxial coefficient of linear thermal expansion (CLTE) of these systems can be systematically changed through large negative to positive values.

A three year PDRA on the Crystallography of multiferroic materials is available within the group.

The group has been awarded a three year, £380k EPSRC grant on ““Novel Multiferroics Perovskites through Systematic Design”. As part of this grant we will be recruiting a Postdoctoral research fellow for a three year post that will focus on the crystallography of multiferroic materials. What this space for more details!

The phonon–glass electron crystal concept is one of the key guiding principles for the development of efficient thermoelectric materials.

We report the high pressure synthesis of a layered perovskite Ca2GeO4 which is found to have the Ruddlesden–Popper structure with I41/acd symmetry.